4/17/2023 0 Comments Electron domain geometry![]() ![]() That’s how we determine that the electron geometry of CH4 is tetrahedral. The single bonds, in this case, are 4 and the number of lone pairs is 0. Hydrogen atoms donate 4 electrons, which means there are a total of 8 electrons around C. The central atom here is C, and there are 4 valence electrons. We can determine it through VSEPR theory, according to which, electron domains repel each other. ![]() Through electron geometry, we get the spatial arrangement of the lone pairs and bond in the molecule. Principle: Electron pairs around a central atom arrange themselves so that they can be as far apart as possible from each other. Remember to draw a Lewis structure to support. ![]() We calculate the number of total electron pairs in electron geometry and not in molecular geometry.ģ. Question: 1) Determine the electron domain geometry AND the molecular geometry of the following molecules. In molecular geometry, though, we only consider bond electron pairs.Ģ. We consider both lone electron pairs and bond electron pairs while determining the shape of a molecule in electron geometry. Electron Geometry vs Molecular Geometryġ. So, when you compare them, you will note that atoms have different arrangements in electron geometry and molecular geometry. It is the 3D arrangement of all the atoms in a particular molecule. Molecular geometry, on the other hand, helps us understand the entire atom and its arrangement. To help you out, we are shedding light on electron geometry vs molecular geometry in this article.Įlectron geometry teaches us about the arrangement of different electron groups. However, a few concepts can be slightly difficult to comprehend because they seem similar or because they are just confusing! One such concept is the difference between electron geometry and molecular geometry. ![]()
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![]() ![]() In Matthew 19:11-12, as Jesus upholds marital permanence he also teaches that some choose to remain single. Christologically Jesus ties the created order to the new age by his teaching and redemptive work on the cross, and by his resurrection. Jesus understood the nature of male lust (Matthew 5:28) and taught that these temptations must be dealt with by confronting the evil within (Mark 7:20-3), yet Jesus own life was without sin (Hebrews 4:15). Jesus regarded women as equal at a time when they didn’t share such a status (Matthew 5:31-32 Luke 7:36-50). Jesus knew the pain of going without the security and comfort of a home and family (Matthew 19:29). He displays the full range of emotions including love of friends (John 11:36, 15:15 19:26). He is the complete and whole single person.Īs a human male, Jesus is completely sexual. The central figure in the New Testament is a single man, Jesus is the model of perfect humanity. The gospels give concrete examples and how he relates to his family, to his friends, and to individuals, both male and female. ![]() He is the complete and whole single person. Jesus is the perfect person, who is perfectly single. ![]() The incarnation of Christ and his bodily resurrection critiques dualistic anthropologies and affirms the body as essential to human personhood. Yet we know that marriage is stitched into the blessings of God contained in the overarching promises of God, so that this starts giving us some hints at what might happen in the New Testament.Ī Trajectory Moving through the New Testament Yet we know that marriage is stitched into the blessings of God contained in the overarching promises of God, so that this starts giving us some hints at what might happen in the New Testament. The Old Testament era see people place marriage to such an ideal as an essential relationship, that singleness may be seen as not a gift as such. In the Old Testament context, to marry and have children is a sacred duty, and to not undertake this is either culturally an anomaly or tragic. Jeremiah doesn’t have a wife (Jeremiah 16:2), Ezekiel’s wife dies (Ezekiel 24:18) and we see their God given role is to communicate as prophets how much God suffers because of his burning love for his people (Jeremiah 18:13-15 Ezekiel 24:13, 24). We observe there is a select group of singles. In the patriarchal structure, single people would remain in the family for their protection and their livelihood. The continuity of God’s future blessing is linked to one’s children, and to be without children was seen as tragedy. There is a strong connection between the themes of offspring, land and name (2 Samuel 9, Ruth 9:4-10). On its own it’s also an age where the pain of singleness is more acute due to the blessing that is tied to family. The Old Testament era is one in which the promise of blessing given to Abraham points forward to a time of blessing for Israel and eventually all nations. Not only within the marriage of man and woman are there distortions on God’s intention for his created order of marriage (Genesis 3:16), but there is also now a distortion to what is intended for the single person. Painful singleness can be related beck to the effects of the fall. With the entry of sin thereafter is death and the disruption of relationships between the sexes. Within this family unit, single people experience the security of the extended family and the community. God creates marriage a secure family unit for the establishment of tribes, cities and nations. This is the start of human community with family, friendships, communication and co-operation. In Genesis 1-2, the pinnacle of the one flesh union of marriage is explained in Genesis 2:24. If the apostle Paul says of the single state that the person who does not marry does even better (1 Corinthians 7:38), then what is the theological blessing of singleness?Ī Trajectory Starting in the Old Testament Every person born onto the earth was once single, it is an aspect of life that at some point everyone has experienced to a certain extent. ![]() Under the grace of God, humanity enjoys many blessings. The Apostle Paul was single, and wrote about having learned the secret of being content, so for our love of single sisters and brothers among us I pray that this essay would be equipping and encouraging for all our church. There is so much to explore and discover in the Bible on contentedness, including our experiences of singleness. Last week’s sermon we heard how we can learn the secret of being content in whatever situation we find ourselves in. ![]() 4/17/2023 0 Comments Age of empires ps4![]() ![]() Because of this, it is important to mix in Hussars along with the heavy cavalry. The lack of Heresy is unfortunate, as the Persians rely on expensive Heavy Cavalry units that are prone to conversion: the Paladin and the War Elephant. ![]() The Persian Monks are among the weakest of all civilizations. But once they hit Imperial Age, the lack of Shipwright can be unfavorable in longer games, and the lack of Bracer for their Galleons does not go unnoticed. In the water, the Persian navy is above average through the Castle Age, thanks to the faster working rate of their Docks. They also have access to a large variety of siege weapons, but they lack Siege Engineers. Thanks to Kamandaran, their Archers have no gold cost, making them weak but cheap units, which pair well with cavalry due to countering Camel Riders and Halberdiers. Still, the Persians can utilize fully upgraded Halberdiers and Hand Cannoneers. Infantry are weak for Persians, and their archer units are not very prominent, due to missing important upgrades such as Bracer, Two-Handed Swordsman, and Arbalester. And these food- and gold-intensive Cavalry units are sustained thanks to faster-working Town Centers, which provide Persians with a quick economic boom that aids into achieving the required Villager production of their key units. They are the only civilization with access to Hussars, Paladins, and Heavy Camel Riders, with all their Stable and Blacksmith upgrades, which also benefits their unique unit, the War Elephant. Stun your enemies with a stampede of mahouted War Elephants and hails of arrows thick enough to blot out the sun while your Savaran ride them down, or field an army of gunpowder units worthy of the great Safavid Empire. ![]() Even after the Muslim conquest, the Sasanian legacy lived on in the structure of the medieval Persian states. "Emerging from inner Persia, the House of Sasan toppled feeble Parthia, establishing a dynasty capable of challenging their Roman neighbors to the west. ![]() 4/17/2023 0 Comments Moebius empire rising full score![]() ![]() Many of the puzzles are conventional to the genre, such as looking for hidden keys and passcodes, or moving objects into a certain order. Moments like this make progress tedious and contrived without providing any clear gameplay advantage.ĭifficult puzzles are rare there were few occasions when I was stumped. In another sequence, I had to leave a conversation and travel from Washington, DC, by plane to New York to pick up a pair of earrings and a bottle of alcohol before flying back to continue said conversation. ![]() In one instance, I had to travel across Manhattan from Central Park to Malachi's apartment to grab an MP3 player, and then travel back, because he wouldn't let me get the device earlier. The limitation makes narrative sense, but it causes issues later in the game. Gather evidence to link characters to famous historical figures. ![]() He sometimes lets items be until the use for them becomes apparent. After all, it's normal in games in the genre for characters to pick up anything lying around, from paper clips to wads of chewed gum, and then rub them against objects to progress, but to Malachi, it's unnecessary. Malachi often refuses to pocket every loose item, which falls in line with his stoic personality. Items that you pick up are stored in your inventory and, when necessary, are used or combined to solve puzzles.Īcquiring items isn't as typical as in other adventure games. The in-game menu lets you briefly highlight points of interest, removing the need to blindly click around the environment. Puzzle solving and exploration adhere to the traditional point-and-click formula, where mouse clicks allow for movement and interacting with objects. They travel through the cities of New York and Boston, walk the sandy streets of Cairo, and explore the dank recesses of ancient catacombs under Paris. The story moves at a brisk pace, with the two protagonists traveling the world in search of their quarry, all the while being targeted by mysterious men in masks who always seem to be one step ahead of them. Searching environments yields clues to be used in your investigations. ![]() Together, they find themselves in a race against time hunting down their targets before a shadow group discovers them first. Malachi soon finds himself paired with ex-soldier David Walker, whom he hires as a bodyguard. The organization believes that these individuals are destined to re-create a certain past event, bringing about a second Golden Age. His abilities earn him the attention of a secret branch of the government, which hands him the task of identifying and attaining special persons of interest who resemble particular people in history pivotal in changing the course of the world. His coveted skills in art appraisal have him traveling the globe to evaluate ancient artifacts and search them for signs of authenticity or fraud. Malachi Rector, the protagonist in this point-and-click adventure, is a brilliant man of considerable ego and antipathy. The plot, crafted by game design veteran Jane Jensen, has all the fluff and dramatic flair of a Dan Brown novel. But the brief moments of exuberance are hampered by mundane puzzle solving and uninteresting characters, making this 10-hour adventure not worth the time spent. At first blush,the story seems intriguing. The game presents a theory that space and time are connected in a twisted loop, and at any given moment, important figures from the past reemerge, sparking an event that may change the world for good or ill. The axiom is often used by politicians and history professors as a warning, but the story behind Moebius: Empire Rising suggests we may not have a choice. It is said that those who cannot remember the past are condemned to repeat it. ![]() 4/17/2023 0 Comments Hot wheels race off download![]() ![]() ![]() You can follow above instructions to install Hot Wheels: Race Off for PC with any of the Android emulators available. You can either install the app from Google PlayStore inside the emulator or download Hot Wheels: Race Off APK file and open the APK file with the emulator or drag the file into the emulator window to install Hot Wheels: Race Off for PC. Everything you love about Hot Wheels brought to life in an awesome racing game. Hot Wheels Race Off Glow Wheels New Cars Pixels 282K subscribers Subscribe 4.3K Share 542K views 1 year ago Hot Wheels Race Off Glow Wheels New Cars Please Help us reach 500 000.CHALLENGE YOUR FRIENDS and the world in. Hot Wheels: Race Off is pure adrenaline sure to get your heart racing. UPGRADE AND BUILD YOUR COLLECTION of Hot Wheels cars. BLAST OFF of boosters, loops, and jumps to stunt on the iconic Hot Wheels orange track - UPGRADE AND BUILD YOUR COLLECTION of Hot Wheels cars - CHALLENGE YOUR FRIENDS and the world in competitive multi-player mode. BLAST OFF of boosters, loops, and jumps to stunt on the iconic Hot Wheels orange track. Race 20+ Hot Wheels cars across 40+ racing tracks, use boosters, loops, and jumps to stunt on the Hot Wheels orange track, upgrade and build your cars, and challenge anyone in competitive multi-player mode. RACE 25+ Hot Wheels cars across 50+ insane physics racing tracks. Hot Wheels: Race Off brings the childhood fun of racing your Hot Wheels cars to your Android devices. Associate or set up your Google account with the emulator. Everything you love about Hot Wheels brought to life in an awesome racing game.Open the emulator software from the start menu or desktop shortcut in your PC.How to Download and Install Hot Wheels for PC or MAC: Select an Android emulator: There are many free and paid Android emulators available for PC and MAC, few of the popular ones are Bluestacks, Andy OS, Nox, MeMu and there are more you can find from Google.Ĭompatibility: Before downloading them take a look at the minimum system requirements to install the emulator on your PC.įor example, BlueStacks requires OS: Windows 10, Windows 8.1, Windows 8, Windows 7, Windows Vista SP2, Windows XP SP3 (32-bit only), Mac OS Sierra(10.12), High Sierra (10.13) and Mojave(10.14), 2-4GB of RAM, 4GB of disk space for storing Android apps/games, updated graphics drivers.įinally, download and install the emulator which will work well with your PC's hardware/software. Hot Wheels: Race Off Race, stunt, and collect in an epic new game from Hot Wheels Download APK Use APKPure App Get Hot Wheels: Race Off old version APK for Android Download Previous versions V2 105.5 MB XAPK APKs Hot Wheels: Race Off 2 Variants V8 105. Let's find out the prerequisites to install Hot Wheels: Race Off on Windows PC or MAC computer without much delay. Hutch Games published Hot Wheels: Race Off for Android operating system mobile devices, but it is possible to download and install Hot Wheels: Race Off for PC or Computer with operating systems such as Windows 7, 8, 8.1, 10 and Mac. Download Hot Wheels: Race Off PC for free at BrowserCam. Race Off 3.4.01 80.6 MB Download Race Off 3.4.0 65.7 MB Download All Versions Games like Race Off Hot Wheels Ultimate Garage 10.0 Hot Wheels® TechMods Bimbo Hot Wheels Racing Hot Wheels Extreme Stunt Race 10.0 Rocket League® Hot Wheels® RC Rivals Set 6.9 Hot Wheels id 8. ![]() 4/17/2023 0 Comments Im pro for windows 8![]() Microsoft Windows 8 accompanies another store for applications, the Windows Store. You can also Download Windows 8 All in One ISO if you are interested in multiple editions in single ISO. Whatever sort of PC you have, you’ll find snappy and liquid courses to switch between applications, move things around, and go easily from one place to a different one. Windows 8 is immaculate for PCs with just a rodent and console, those with touchscreens, and those with both. Tiles on the Start screen of Microsoft windows 8 are joined with individuals, applications, organizers, photographs, or online sites, and are buzzing with the most cutting edge insight, so you’re cutting-edge at a look. This is final bootable ISO Image of Download Windows 8 Pro DVD Disk for x86 圆4 PC.Įverything you think about above all is on the new Windows 8 Start screen. Else you may have to disable both and use on screen keyboard if you need the control key.Download Windows 8 Pro ISO 32 Bit / 64 Bit Free official untouched. So you should find which of the two ctrl keys is causing the problem and disable one of them using this software. However for a permanent fix, I downloaded SharpKeys and disable the Right Control, this has solved the problem. If it still does not work, opening the on-screen keyboard from control panel can temporarily unlock the ctrl key
4/17/2023 0 Comments Download hype pro 3 tumult![]() ![]() ProprietaryMacWindowsLinux33 alternatives to Google Web Designer Google Web Designer is a a program from Google for creating interactive HTML5 ads and other HTML5 content for any device.Suggest and vote on featuresGlaxnimate Features Automated TweeningGlaxnimate can automatically generate the inbetweens from two keyframes, to carry out a smooth transition. Keyframe AnimationCompositions can be keyframed in Glaxnimate, allowing you to change the parameters over time. Support for scriptingGlaxnimate supports scripts and macros to automate or customize tasks. Extensible by Plugins/ExtensionsGlaxnimate can be extended with add-ons, plugins and extensions. Support for LayersGlaxnimate supports the organization of elements through a hierarchical order that can be manipulated/viewed independently. Dark ModeGlaxnimate supports dark mode for comfortable usage in low light conditions.Animate Vector IllustrationsExport to SVGPlugin APIVectorize raster images 64Google Web DesignerIs this a good alternative? Yes NoCopy a direct link to this comment to your clipboard Free Open SourceAnimation MakerVector Graphic AppMacWindowsLinux11 alternatives to Glaxnimate Glaxnimate is a vector graphics animation program which focuses on being quick and easy to use.Suggest and vote on featuresAdobe Animate Features Keyframe AnimationCompositions can be keyframed in Adobe Animate, allowing you to change the parameters over time. Pressure SensitivityAdobe Animate can change attributes like thickness or opacity, based on how much force you apply to your stylus/finger. Animation RiggingAdobe Animate supports bone structures to manipulate a 3D model like a puppet for animation. Support for LayersAdobe Animate supports the organization of elements through a hierarchical order that can be manipulated/viewed independently. Onion skinningAdobe Animate allows you to see through several frames simultaneously and make sure the lines of each frame are correctly lined up. Works OfflineAdobe Animate can be used without the need to connect to the internet. Support for scriptingAdobe Animate supports scripts and macros to automate or customize tasks. Automated TweeningAdobe Animate can automatically generate the inbetweens from two keyframes, to carry out a smooth transition.Export to SVGVideo MakerDrawing 2D 11GlaxnimateIs this a good alternative? Yes NoCopy a direct link to this comment to your clipboard Free ProprietaryAnimation MakerMacWindows54 alternatives to Adobe Animate Adobe Animate, previously Adobe Flash Professional, is an authoring environment (IDE) that can produce interactive solutions for running inside web browsers or for the desktop.Suggest and vote on featuresDesygner FeaturesVisual designCustom templatesMultiple languagesSocial media integration 108Adobe AnimateIs this a good alternative? Yes NoCopy a direct link to this comment to your clipboard Paid ProprietaryGraphic Design ToolWebsite BuilderOnlineAndroidiPhoneAndroid TabletiPad143 alternatives to Desygner Desygner is an online and mobile design solution, which offers a simpler alternative to expensive and complicated design suites.Animations and interactive content made with Hype work on desktops.Learn more about HypeHype info, screenshots & reviewsAlternatives to Hype29 FiltersWindowsShow more filters 52DesygnerIs this a good alternative? Yes NoCopy a direct link to this comment to your clipboard Freemium ![]()
4/16/2023 0 Comments Midi patchbay pedal![]() Sorry being a bit terse as I've only got a moment but you get the idea. For patching balanced analogue audio, professional studios have traditionally employed Bgauge or ‘longframe’ patchbays. Kenton Line Drivers change all that with 500m of ultra-reliable, bi-directional MIDI transmission. ![]() MIDI Line Drivers With a maximum recommended cable length of 15m, it isnt always easy to use MIDI on big stages and large productions. Now just use a bunch of short, standard patch cables to route shit back and forth between all the jacks on your board. New Product Coming soon: the Kenton Interchanger MIDI patchbay. When you think of the layout on the board it's probably worth putting all the inputs in one group and all the outputs in one group etc but you already know this Yet another useful option is to link several rear sockets together to create a Mult or Parallel strip at the front of the patchbay, providing a convenient means of routing one source to several. zip tie all the shit inside the patchbay together nicely or whatever so you don't pull 'em off.Ĭoming out of the underside of the patchbay will now be a whole bunch of patch cables. A lot of mixers and guitar pedals use the halfnormalling arrangement for the left and right inputs, allowing mono sources to feed both channels. chop the plug off of one end, get down to the exposed wires and solder them to the lugs of one of the jacks in your patchbay Get yourself as many patch cables as there are holes. Midisport 2x2 and 4x4 series are a good example. An interface usually allows MIDI In/OUT messages to route to and from a computer based DAW to your hardware outboard synths, etc.no patching usually Midi interfaces are of course, still around. Install 1/4" (or 1/8" or whatever) jacks into all the holes A patchbay allows any MIDI in to route to any MIDI Out. Take a square piece of wood or metal that is big enough and drill a bunch of holes into it ![]() If all you wanted to do was bring all the input and output jacks from the pedals onto a single field it would be really easy to do ![]() 4/16/2023 0 Comments App tamer with vpn![]() ![]() While the selling point for ProtonVPN might be its free tier, it's probably not the best bet if you value speed and reliability. It's also the only option on this list with a free tier, which provides a fantastic starting point if you're new to VPNs. ProtonVPN grew from the team behind ProtonMail, a crowdfunded project dedicated to widespread online privacy. In that case, you'll want a VPN that offers the most server locations for a consistent VPN connection and a kill switch if you accidentally access unsecured public Wi-Fi networks. For example, suppose you travel a lot but aren't fussed about internet speed. Consider your situation carefully when selecting a VPN. Some offer faster speeds, while others have more server locations for consistent connections. But what should you look for when the top VPNs offer the same core service?ĭespite the same core service, each VPN provider has unique functionality. Once you've familiarized yourself with VPNs, you're ready to choose one. This tells you everything you need to know, explains terms like split tunneling and kill switches, and provides a breakdown of the most common VPN protocols, including OpenVPN, WireGuard, and ikev2. If you're unfamiliar with VPNs, we recommend reading our VPNs for beginners guide. We recommend installing and using a VPN on all devices with internet access, including iPhones, desktop PCs, and budget Android tablets. We discuss what each VPN offers and what features to look for across all VPNs. ![]() Expensive but still the best.There are a lot of VPN services, so we rounded up the best VPNs into one list. ShareMouse - use 1 keyboard for multiple computers. PowerPhotos - best iCloud photos/photos power app PopClip - excellent productivity app to show little selection actions Plex Media Server - Plex sucks but it's still the best. PhraseExpress - Excellent text replacement app Permute 3 - cool automation app for converting. PCalc - for advanced math functions, I use Pcalc For advanced finder workflows, PathFinder is it Path Finder - for basic use, I use forklift. Movist Pro - excellent alternative to IINA. 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Fudenberg released the reports the next day. In the same hearing, Williams ordered the coroner to release autopsy reports of the 58 people Paddock killed at the Route 91 country music festival in the worst mass shooting in modern American history. Last week, at the request of the Review-Journal and The Associated Press, District Judge Timothy Williams ordered Clark County Coroner John Fudenberg to turn over Paddock’s autopsy records to the news organizations, but Fudenberg refused to release it until it was finalized. Police have yet to determine a motive for the shooting, and speculation has swirled about mental or physical health conditions that might have provided clues to his violent behavior. The results of the autopsy and brain examinations have been long anticipated. Lisa Gavin of the Clark County coroner’s office. ![]() Paddock, 64, also had hypertensive cardiovascular disease, according to the autopsy report, which was prepared by Dr. There was no mention in the results of substances associated with alcohol. Paddock also had scrapes on his right upper calf and knee and a bruise on his left calf.Ī separate examination of his brain done at Stanford University found no major abnormalities, including no evidence of Alzheimer’s disease.Īmounts of nordiazepam, oxazepam and temazepam, which are consistent with the anti-anxiety drug Valium, were found in his urine, a toxicology report shows. The bullet that killed Paddock entered the roof of his mouth and traveled to the back of his head and then upward without exiting his body, leaving fractured bones along the way, the report says. “We may never understand why Steve did this.” “It seems that based on the autopsy reports there were no physical excuses for what Steve did,” said his younger brother Eric Paddock, who lives in Orlando, Fla. It also confirmed what authorities had previously said - that Paddock died of a self-inflicted gunshot wound to his head after he opened fire at an outdoor concert from his 32nd-floor Mandalay Bay suite, killing 58 people and injuring hundreds more. ![]() The autopsy, which included toxicology tests and a brain examination, found that Paddock had anti-anxiety medication in his system. (John Locher/AP)Īutopsy records obtained Friday by the Review-Journal shed no new light on what might have contributed to Stephen Paddock’s motives for committing the Oct. Authorities said Stephen Paddock broke the windows and began firing with a cache of weapons, killing dozens and injuring hundreds. Windows are broken at the Mandalay Bay resort and casino, Tuesday, Oct. ![]() |
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